I've heard that basically everywhere you go in space you will die by overheating because your body can't radiate away the heat it generates. It's weird to think that you can die from literally being cooked alive in a vacuum with a temperature of 0 degrees (readers choice of units).
Temperature is one of the least intuitive things when really getting into the nitty gritty of it. One of my favorite things to prompt people with is to ask them what makes something twice as hot as something else?