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FWIW water grows less mould than water with sugar/flavor/etc.
Assuming USA, kleen kanteen, with a simple screw-off cap. Or yeti with those slider caps. Personally as a desk worker my water jug has no cap.
For cleaning, soaking for 20 min or so with hot water and something like unscented oxyclean, powder brewery wash, or a bit of dishwasher powder works very well at removing organic matter - for stainless and glass.
I love brewery wash for my water bottle! Soap or bleach always seemed to give me a funny taste or order. It may have been in my head, but I didn't like it and it led me to cleaning it less often.
Decided to hit it with StarSan one time it got icky and cleaned it right up with no taste or smell.
I try to run it through the dishwasher more often, but if I put something odd in the bottle or it sat out for a long time, now I StarSan it.
I am very bad at remembering to clean my water bottles regularly, I have about 4 nalgene bottles and a CamelBak in fairly regular rotation, they get left in the car, sometimes with water in them, sometimes empty but rarely totally dry, often for days, weeks, or even moths at a time. I don't drink water that's been sitting in my bottles for that long, but I've never noticed any weird smells, scum, cloudiness, mold, etc when I go to empty them.
And I can't say I've ever had an issue with mold or any other funkiness in any of my bottles.
And I think a lot of it is that I only put water in my bottles, no flavorings or anything else (except maybe occasionally iodine or other water purification products when I'm camping, which of course is just going to kill anything that would start growing in there otherwise)
I also usually (but not always) fill them with purified water to begin with.