Final Sacrifice & Space Mutiny are at the top of my list, but I've rewatched them so many times I can just about recite them line for line from memory. Same with Mitchell & Sidehackers.
I've started more carefully watching episodes that I may have originally written off as boring or too awful to bear & I keep discovering new hilarious riffs that I missed on the first or second watch. So I'm discovering new favorites as I go. e.g. I watched Lost Continent earlier today & was in tears.