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This 9v battery contained six cells stacked like a layer cake
(lemmy.sdf.org)
Picture of a disassembled Duracell 9v battery. Below the terminal assembly is a clear plastic case where you can see six sets of stacked rectangular terminals and fillings.
I had an old 12v power tool battery die, so I took it apart to find 8 generic AA rechargeables wired together. I suspect lots of batteries are multiples of 1.5v (9/12/18) because they're just stacked smaller cells that are already mass produced.
Battery chemistry produces fixed voltages depending on what you use. It depends on where the active components sit on the electronegativity table.
The typical ones are:
Zinc-carbon and alkaline - 1.5 volts per cell.
Lead acid - 2 volts
Nickel Cadmium - 1.2 volts
Nickel Metal Hydride - 1.4 ish.
All the Lithium ion combos - 3.4 to 3.7 volts.
Lipo is something like 3.4ish to 4.2v
The voltage range depends a lot on cell construction, temperature, load or charge rate, and chemical mix.
For example "lead acid" batteries with lead and sulphuric acid have a cell chemistry voltage of 2.05 volts but their nominal range is 1.8 to 2.4 volts per cell. Translating that to a 6 cell "12 volt" car battery gives you a range of 10.8 to 14.8 volts.