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The @ Sign Has Been Around Since 1536, So What Was It Used For Pre-Internet?
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The article explains it, but the origin is from Latin ⟨ad⟩ for, toward, at in the Middle Ages. Faster to write, less paper and ink necessary (those can be expensive).
There's a bunch other symbols and diacritics that popped up back then, for roughly the same reasons. From what I recall:
*old spellings. Modern ⟨dieci⟩ and ⟨piño⟩ / ⟨pinho⟩ respectively.