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Humans can be tracked with unique 'fingerprint' based on how their bodies block Wi-Fi signals
(www.theregister.com)
This is a most excellent place for technology news and articles.
It is cool for home automation if you can turn it into a presence detection software (do not connect your Homeassistant to the internet though)
If all you need is presence detection then a motion sensor would be vastly more efficient.
If you actually need identity detection, then maybe, but you'll still have to have a camera or detailed access logs to associate the interference signature with a known entity and at that point you may as well just put an RFID reader under the bowl you throw your keys into or use facial or gait detection.
A motion detector is far more inferior to precense detectors, most just use milimator wave though.