Our idea of "warm" colors is just a historical accident. Wood burns orange because it produces soot, which glows orange in the flame. Same applies to candles too, because there’s never enough oxygen to burn all the carbon.
If we’d started with purified hydrocarbons instead, blue might have been the ultimate "warm" color. Natural gas burns with a blue or even invisible flame, a sign of complete combustion. Orange, then, would be the color of flawed, struggling fire.
Imagine a house heated and lit by a gas furnace instead of a traditional fireplace. The light from the fire would be blue, and we’d associate that glow with warmth and coziness. Picture old paintings with a cozy atmosphere, their hearths glowing blue. If everyone grew up like that, blue would be the warmest color instead of orange.
"Different flame types of a Bunsen burner depend on oxygen supply. On the left a rich fuel with no premixed oxygen produces a yellow sooty diffusion flame; on the right a lean fully oxygen premixed flame produces no soot and the flame color is produced by molecular radicals, especially CH and C2 band emission."
Source: Wikipedia
Our perception is limited and our understanding has long outgrown it. White light, by definition is all visible light at equal intensity, thus the sun is NOT white.
Use RGB codes for example. White, by definition would be 255, 255, 255.
The Sun is more like 245, 253, 255 or something .... still looks white enough to us, but by definition, isn't.
Can we agree it's not orange? That is what I was originally pointing out.
From a physical standpoint, sure.
But I'm pretty sure that if you casually ask most people which colour the sun is, you'll hear yellow/orange much more often than white. So for the context of which colour was, prehistorically, associated with warmth I think yellow/orange are the more relevant answers.